Bleach

Season 1, Episode 239

Episode Title: The Awakening Hyōrinmaru! Hitsugaya's Fierce Fight

Air Date: 2009-09-29

Overview:

As 5th Division Lieutenant Momo Hinamori and 10th Division Lieutenant Rangiku Matsumoto conclude their battle, 10th Division Captain Tōshirō Hitsugaya tries to convince Hyōrinmaru he is his master, but the Zanpakutō Spirit does not believe it.